Poly(ε-lysine) and its derivatives <i>via</i> ring-opening polymerization of biorenewable cyclic lysine
نویسندگان
چکیده
Minireview focused on poly(ε-lysine) and its derivatives via ring-opening polymerization of biorenewable cyclic lysine.
منابع مشابه
Organocatalytic ring-opening polymerization.
Modern synthetic methods have revolutionized polymer chemistry through the development of new and powerful strategies for the controlled synthesis of complex polymer architectures.1-5 Many of these developments were spawned by new classes of transition metal catalysts for the synthesis of new polyolefin microstructures,5 the design of highly efficient families of “living” polymerization strateg...
متن کاملInvestigations into Apopinene as a Biorenewable Monomer for Ring- Opening Metathesis Polymerization
The ring-opening metathesis polymerization (ROMP) of apopinene is reported. We find that apopinene reacts with Rubased metathesis catalysts to provide an all trans-polymer with a polydispersity index (PDI) as low as 1.6 and molecular weights in the 1100 to 15 600 g·mol−1 range (9−127 monomer units). Because apopinene is readily prepared in one-step from myrtenal or two-steps from α-pinene, both...
متن کاملThermodynamics and Kinetics of Ring - Opening Polymerization
Cyclic monomers that have been polymerized via ring opening encompass a variety of structures, such as alkanes, alkenes, compounds containing heteroatoms in the ring: oxygen [ethers, acetals, esters (lactones, lactides, and carbonates), and anhydrides], sulfur (polysulfur, sulfi des and polysulfi des), nitrogen [amines, amides (lactames), imides, N carboxyanhydrides and 1,3 oxaza derivatives], ...
متن کاملBiological activity of amide derivatives of lysine.
Five substituted amides of lysine with the general formula: X-Lys-NH-Y, where X= acetyl or ethoxycarbonyl, Y= cyclohexyl, benzyl, hexyl or cadaverine residue were synthesised and their effects on fibrinolytic activity of plasmin, clotting activity of thrombin and amidolytic activities of both enzymes were examined.
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ژورنال
عنوان ژورنال: Polymer Chemistry
سال: 2021
ISSN: ['1759-9962', '1759-9954']
DOI: https://doi.org/10.1039/d0py01387k